Star polymers in shear flow.
نویسندگان
چکیده
Linear and star polymers in solution are studied in the presence of shear flow. The solvent is described by a particle-based mesoscopic simulation technique, which accounts for hydrodynamic interactions. The scaling properties of the average gyration tensor, the orientation angle, and the rotation frequency are investigated for various arm lengths and arm numbers. With increasing functionality f, star polymers exhibit a crossover in their flow properties from those of linear polymers to a novel behavior, which resembles the tank-treading motion of elastic capsules.
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عنوان ژورنال:
- Physical review letters
دوره 96 18 شماره
صفحات -
تاریخ انتشار 2006